Significance of material technology for plant life management in nuclear power plants

The life-limiting mechanisms for components and systems are physical aging and wear. Both of them are related to changes of microstructure in the bulk material or at the phase boundaries medium/material and material/material. They are triggered during operation by factors such as temperature, mechanical load, and environment. Thus, to achieve an utmost effective aging management it is necessary, to understand the underlying aging and wear mechanisms such as neutron irradiation, fatigue, corrosion, fretting, etc. Definition and qualification of suitable corrective and preventive actions against accelerated aging, requires precise knowledge of the aging processes and life-limiting situations and thresholds. It is obvious, then, that materials engineering plays a large part in effective and economical plant life management. Within this paper, the role of materials science and technology in plant aging management during the various stages within a whole life cycle of a power plant is described: (1) the correct choice of materials as part of a well-based materials concept in the design stage is very important for later plant operation. As an example steam generator materials are presented. (2) The parameters of the individual manufacturing processes during erection of components and systems must be optimally selected in order to guarantee long-term operation. As an example the reasons for core shroud cracking in a BWR NPP are discussed. (3) Aging mechanisms must be accounted for in operation of components and systems, and their effects have to be counteracted in order to prevent service-life limiting situations. Details are described with respect of corrosion and neutron irradiation. Demanding future tasks for materials science and technology are presented, which are necessary to continue to contribute to an optimized plant life management and to cost-effective operation of nuclear power plants at high safety levels.     

Modification of CaCO3 precipitation rates by water-soluble nacre proteins

Mineral growth in nacre and other CaCO₃-containing biominerals is controlled by biopolymers. Water-soluble proteins were extracted from nacre of the sea snail Haliotis laevigata by dissolving the mineral phase with 6% acetic acid. The influence of this protein mixture on CaCO₃ precipitation rates was investigated at different concentrations. A well-established assay for measuring the pH-value during CaCO₃ precipitation with and without protein additives was extended by calculating maximum precipitation rates from the pH-values. It could be shown that precipitation rates are greatly influenced by the mixtures of water-soluble nacre proteins. At very low protein concentrations (0.02 μg/ml) a rate enhancement in comparison to the pure supersaturated calcium carbonate solution by a factor of 1.4 was observed. At higher protein concentrations, a strong inhibitory effect occurred, with total inhibition at concentrations of 1.0 μg/ml and higher. Two unspecific proteins (bovine serum albumin and lysozyme) showed little or no modification of precipitation rates. In vivo, the function of the strong inhibition of CaCO₃ precipitation by nacre proteins at higher concentrations is presumably to prevent uncontrolled crystallization in the extrapallial fluid. The rate-enhancing capability of proteins at low concentrations may be explained by the presence of acidic and/or hydrophilic moieties.     

Impacts of CO2 emission constraints on technology selection and energy resources for power generation in Bangladesh

This paper examines the impacts of CO₂ emission reduction target and carbon tax on future technologies selection and energy use in Bangladesh power sector during 2005–2035. The analyses are based on a long-term energy system model of Bangladesh using the MARKAL framework. The analysis shows that Bangladesh will not be able to meet the future energy demand without importing energy. However, alternative policies on CO₂ emission constraints reduce the burden of imported fuel, improve energy security and reduce environmental impacts. The results show that the introduction of the CO₂ emission reduction targets and carbon taxes directly affect the shift of technologies from high carbon content fossil-based to low carbon content fossil-based and clean renewable energy-based technologies compared to the base scenario. With the cumulative CO₂ emission reduction target of 10–20% and carbon tax of 2500 Taka/ton, the cumulative net energy imports during 2005–2035 would be reduced in the range of 39–65% and 37%, respectively, compared to the base scenario emission level. The total primary energy requirement would be reduced in the range of 4.5–22.3% in the CO₂ emission reduction targets and carbon tax 2500 Taka/ton scenarios and the primary energy supply system would be diversified compared to the base scenario.